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New superconductors, Li$_x$(C$_n$H$_{2n+3}$N)$_y$Fe$_{1-z}$Se ($n$ = 6, 8,18), have been synthesized via the co-intercalation of linear monoaminestogether with Li into FeSe. The distance between neighboring Fe layers expandsup to 55.7 {\AA} for n = 18, which is much larger than the previous record of19 {\AA} in the FeSe-based intercalation superconductors. Tc remains saturatedat $\sim$42 K.

journal of the physical society of japan

Synthesis of New Lithium- and Monoamine-Intercalated Superconductors  Li$_x$(C$_n$H$_{2n+3}$N)$_y$Fe$_{1-z}$Se ($n$ = 6, 8, 18) with the  Dramatically Expanded Interlayer Spacing