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Oxygen $K$-edge X-ray absorption spectroscopy measurements were conducted onT*-type La$_{1-x/2}$Eu$_{1-x/2}$Sr$_x$CuO$_4$ (LESCO) to estimate the holedensity ($n_{\rm h}$) and investigate the oxidation annealing effect on $n_{\rmh}$. A drastic increase in $n_{\rm h}$ due to annealing was found. The increasein $n_{\rm h}$ cannot be explained solely by the oxygen gain due to annealing,suggesting that delocalized holes are introduced into the CuO$_2$ plane. Aphase diagram of LESCO was redrawn against $n_{\rm h}$.

Revisiting the phase diagram of T*-type La$_{1-x/2}$Eu$_{1-x/2}$Sr$_x$CuO$_4$ using Oxygen $K$-edge X-ray absorption spectroscopy