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We revealed novel phase deagram of Fe-pnictide high-Tc superconductorLaFe(As_{1-x}P_{x})O in wide doping level (0.3<x<1) by P-NMR. Systematic31P-NMR studies revealed the emergence of the antiferromagnetic ordered phase(AFM-2) in 0.4 < x < 0.7 that intervenes between two superconductivity(SC-1/SC-2) phases. The 31P-NMR Knight shift points to the appearance of thesharp density of states at the Fermi level that is derived from d_{3Z^2?r^2}orbit, which is less relevant with the onset of the SC-2. On the other hand, weremark that the AFM spin fluctuations arising from the interband nesting on thed_{XZ}/d_{YZ} orbits must be a key ingredient for the occurrence of SC aroundAFM-2.

Emergence of Novel Antiferromagnetic Order Intervening between Two Superconducting Phases in LaFe(As_1-x_P_x_)O: 31P-NMR Studies