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ubiquitin, and then degraded by a proteasome in an ATP dependent manner1^ The catalytic core of the proteasome is the 20S proteasome. New20S proteasome inhibitors would contribute to further understanding of the system2~4\ In the course of our screening program, wehave isolated several classes of 20S proteasome inhibitors including (i) the novel cyclic peptides, TMC-95s, and (ii) the new members of a',/3'-epoxyketone containing peptides, TMC-86s and

TMC-89A and B, New Proteasome Inhibitors from Streptomyces sp. TC 1087.