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tBu 4 ) prepared using the solution in methylene chloride at different degrees of initial surface coverage (cedge from 10 to 51%) is determined. The significant change of the monolayer structure due to changes in initial conditions is shown. A comparative analysis of the quantitative structure parameters and properties of floating layers of CuThp t Bu 4 prepared using solutions in benzene and methylene chloride is performed. It is shown that in the case of the aromatic solvent (benzene, cedge = 10%) and the azaporphyrin with the disturbed π-system (CuThp t Bu 4 ) intermolecular interactions APwater became prevailing, what leads to formation of dense and rigid monolayers with the most open (face-on) structure of nanoaggregates.

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Influence of the Solvent Nature on the Structure of Two-Dimensional Nanoaggregates in Langmuir Layers of Copper Tetra-tert-butyltetrabenzotriazaporphyrin