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The monoand heteronuclear lanthanide-containing complexes on the basis of 1,3-disubstituted p-tert-butylcalix[4] arenes modified with macrocyclic (porphyrin) and acyclic (benzimidazole) nitrogen-containing fragments were investigated. The optimal conditions of synthesis, compositions and structures of lanthanide complexes with functionalized calix[4]arenes were determined. The influence of the structure of compounds on the spectral-luminescent properties of both the ligands and their complexes was analyzed.

Synthesis and Spectral-Luminescent Properties of Polynuclear Lanthanide Complexes with Functionalized Calix[4]arenes