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Enthalpies of dissolution of tetrapyridylporphyrin (TPyP) derivatives, in which the pyridine nitrogen is located in para-, metaor ortho-positions and is modified by nonpolar (-CH3,-C2H5,-C3H7), polar (-CH2COOH, -CH2CH2COOH) and low-polar (-CH2COOC2H5) groups, are determined in water by calorimetric method for the first time. The factors, making considerable impact in enthalpies of dissolution of the studied compounds in water, are revealed.

Solvation Interactions of Tetrapyridylporphyrin Derivatives in Aqueous Solutions