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Unsymmetrically substituted monophthalocyanines represent considerable interest not only from theoretical, but also from the practical point of view. Functional substitution of various nature in such macrocyclic compounds allows to design new supramolecular structures possessing unique physical and chemical properties.[2,3] For this reason development of the direct synthetic methods for these compounds is one of priority field in phthalocyanine chemistry.

Application of Monohydroxyphthalocyanines for Selective Preparation of Homo- and Heteroligand Macrocyclic Compounds