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Photophysical properties of synthesized 2,6-brominated BODIPY dyes having dithienylenevinylene at 3,5-positions have been investigated in different solvents combining experiment and time dependent density functional theory (TDCAM-B3LYP). This study shows a good agreement between the measured and computed excitation energies with a small deviation of 25-40 nm. The UV-Visible range corresponding to the electronic transition involving HOMO, HOMO1 and LUMO orbitals is also reported. Further, the assessment of the antimicrobial activity of the 2,6-brominated BODIPY and 2,6-brominated BODIPY substituted with distyryl at 3,5-postions has shown that at lower concentrations (3.12∙10-3 mg/mL) these synthesized compounds are able to eradicate E. coli and S. aureus upon 25 minutes irradiation using LEDs shining light at 530 nm and 650 nm.

Photophysical and in vitro Antibacterial Studies of 2,6-Dibromo-BODIPY Dye Substituted with Dithienylenevinylene at 3,5-Positions