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Planar-chiral Nand O-containing macrocycles were obtained via enantioselective Pd(0)-catalyzed amination of 1,5-dichloroanthraquinone and converted into corresponding di(bromobenzyl) substituted derivatives. The latter compounds were introduced in the Pd(0)-catalyzed macrocyclization reactions with several linear oxadiamines and certain pairs of reagents gave macrobicyclic compounds with a central planar-chiral structural fragment.

Pd(0)-Сatalyzed Amination in the Synthesis of Planar-Chiral Macrobicyclic Compounds Comprising 1,5-Disubstituted Anthraquinone Moiety