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An experimental and theoretical study of 5,10,15-triphenylcorrole (H3[(ms-Ph)3Cor]) nano-structured floating layers (M-layers) was performed. The existence areas and characteristics of the structure and properties of stable monomolecular layers were determined. Main dependencies of the M-monolayer on the initial surface coverage degree were identified – the sizes of the nanoaggregate, aggregation number, surface area per molecule in a nanoaggregate, etc. A quantitative model of a monolayer with water and dry M-nanoaggregates was constructed. H3[(ms-Ph)3Cor] thin films on solid substrates were obtained using the Langmuir-Schaefer (LS) technique, and their spectral characteristics were explored.

Formation and Study of Nanostructured M-Monolayers and LS-Films of Triphenylcorrole