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A near-infrared oxovanadium(IV)-α,α’-octapentoxyphthalocyanine (oxo-V(IV)-Pc) has been synthesized and characterized. Solvent-dependent optically spectroscopic and electrochemical investigations including UV-vis absorption and magnetic circular dichroism (MCD) spectroscopy, cyclic voltammetry (CV), DPV and multi-scan rate CV electrochemistry measurements were carried out to give in-depth understanding of the electronic structure of this oxo-V(IV)-Pc. Both α,α’-substituents and solvent polarities have large influence on the electronic structure of this NIR absorbed oxovanadium(IV)-phthalocyanine.

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Effect of Solvent on the Spectroscopic, Electrochemical and Spectroelectrochemical Properties of Near-Infrared Oxovanadium(IV) α,α’-Octapentoxyphthalocyanine