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The first calix[4]arene derivative in cone conformation containing two azidoacetamide groups on the upper rim and two alkyl substituents on the lower rim of the macrocycle was synthesized. It has been shown that this compound is a convenient precursor for the synthesis of broad series of amphiphilic receptors on the calixarene platform in cone stereoisomeric forms using the copper-catalyzed 1,3-dipolar cycloaddition (CuAAC) to terminal alkynes. The formation of 1,2,3-triazoles have been established by oneand two-dimensional NMR spectroscopy. Water soluble bis-ammonium derivative possesses the receptor and surfactant properties. The formation of 2:1 complex (eosin:calixarene) with a negatively charged fluorescent Eosin Y dye was accompanied by a significant quenching of dye fluorescence. This “dark” complex is perspective for the design of the fluorescent sensors for anionic organic substrates, based on the competitive displacement of the dye molecules in the calixarene cavity. Above the critical aggregation concentration (3.3∙10-4 M) two types of nanoaggregates with diameter of 27 and 139 nm are observed, where in the complex stoichiometry remains unchanged.

New Amphiphilic Bowl-Shaped Receptors on the Basis of Calix[4]arenes in Cone Conformation: Synthesis, Self-Aggregation and Eosin Y Dye Binding