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This paper considers the influence of various surfactants and polyelectrolytes on the photophysical properties and the aggregation state of transition metal complexes of meso-5,10,15,20-tetrakis-(4-sulfonatophenyl)porphyrin (MeTPPS). Porphyrin transition metal complex aggregation stability in acidic medium is also compared for a number of metal cations. The mechanism of J-aggregate formation and the nature of porphyrin-surfactant interactions in microorganized systems are discussed in details.

Photophysical Properties and Aggregation Behavior of Transition Metal Tetraphenylporphyrin Tetrasulfonate Complexes in Microheterogeneous Media