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New data are presented on the phase equilibria and crystal chemistry of the binary systems CaO-Bi 2 O 3 and CaO-CuO and the ternary CaO-Bi 2 O 3 -CuO. Symmetry data and unit cell dimensions based on single crystal and powder x-ray diffraction measurements are reported for several of the binary CaO-Bi 2 O 3 phases, including corrected compositions for Ca 4 Bi 6 O 13 and Ca 2 Bi 2 O 5 . The ternary system contains no new ternary phases which can be formed in air at ~700-900 °C.

Phase equilibria and crystal chemistry in portions of the system SrO-CaO-Bi2O3-CuO, Part IV - The System CaO-Bi2O3-CuO