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The equilibrium phase diagram was determined for the Eu 2 O 3 -In 2 O 3 system. An induction furnace, having an iridium crucible as the heating element (susceptor), was used to establish the solidus and liquidus curves. The 1:1 composition melts congruently at 1745 ± 10 °C. Melting point relations suggest that the 1:1 composition is a compound with solid solution extending both to 31 mole percent In 2 O 3 and 71 mole percent In 2 O 3 . The compound is pseudohexagonal with a  H = 3.69 A and c  H = 12.38 A. Isostructural phases also occur in the 1:1 mixtures of both Gd 2 O 3 and Dy 2 O 3 with In 2 O 3 . The melting points of Eu 2 O 3 and In 2 O 3 were determined to be 2,240 ± 10 °C and 1910 ± 10 °C respectively. A eutectic occurs in the Eu 2 O 3 -In 2 O 3 system at 1,730 °C and about 73 mole percent In 2 O 3 . The indicated uncertainties in the melting points are conservative estimates of the overall inaccuracies of temperature measurement.

Phase equilibria in systems involving the rare earth oxides. Part III. The Eu2O3-In2O3 system