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The absor pt ion of hydrogen sulfid e in the region 6, 100 to 6,500 cmI has bee n m easured under high r esolution . The ro tational fine s tru cture has been analy zed t hrough the use of published energy t ables for t he rigid r otor. A classical centr ifugal-distor t ion correction was a ppli ed to the rigid energy levels. It is fo und t hat t here are t wo overlapping bands in this region, a normally strong, Atype band , the (nl' n2, na) = (1,1,1), and a normally weak, B-type band , w hi ch becomes str ong enough to be observed by borrowing in tensity from t he A-type band t hrough a Cor iol is inter ac tion. The B-typ e ba nd is t he lower component of the reso na t ing pair (2,1,0) and (0,1,2). The excited state iner t ial parameters giv in g t he bcs[ fi ts are (1,1,1) band, 11 = 10. 398, B = 8.935, C= 4 .. 5J8, 1-'0= 6289.26 em-I; (0,1,2) band , 11 = 10.:394, B = 8.9 18, C= L547, 1-'0= 6288.28 emI.

Infrared spectrum of hydrogen sulfide in the 6,290-cm-1 region