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The absorption spectrum of water vapor has been measured from 4.5 to 13 microns with a 3,600 line per inch replica echelette grating as the dispersing element. Various absorbing path lengtns and concentrations of water vapor at atmospheric pressure were used up to 8 meters of steam near 110° C. Almost all of the previously imreported lines that have been found are also present in the solar spectrum. A rotational analysis shows thgifc most of the lines can be assigned either to rotational transitions or to rotation-vibration transitions of the V2 fundamental of the water-vapor molecule. In addition, a few lines have also been assigned to the transitions (2* — V2), (Vi — 2), and . (vz — v%).

Absorption spectrum of water vapor between 4.5 and 13 microns