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a Raman value. is the only second harmonic band observed in the spectrum when the 5.0-cm cell was used and indicates that v7 is very intense. The first harmonic band of v2 is fairly intense in the infrared spectrum, and this increase in intensity is brought out by resonance with Vi at 2,993 cm". In the spectrum of dichloromethane 2v2 is weak, as the conditions of resonance are not so favorable. The resolution of some of the bands in the regions of 1.6 and 2.4/x into their rotational structures makes it possible to determine one of the moments of inertia for the molecule. The separation of the rotational lines varies slightly from one band to another. The average spacing of the lines is about 2.4 cm" in the 1.7005/z band. A study of the rotational structure of this molecule and that of dichloromethane and difluoromethane is being made and will be the subject of another report. The spectrum of chlorofluoromethane supports the assignments of the fundamental bands made on the spectrum of dichloromethane. Further experimental work will be necessary to have sufficient data for determining the CC1F angle in this molecule.

Resin bonding of hardwood fibers in offset papers