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From ex perimental data recently obtai ned on the heats of combustion of t he eight CSH I6 a lkylcyclohexanes in th e liquid state at 25° C, together with auxiliary dat.a 011 the differences in the heats of vaporization at 25° C and on t he difference in heat contcnt of t he gas betwcen 0 ° K and 25° C, values are calculated for the followin g prope rties: the heat of isomerization of ethylcyclohexane into the given dimethylcyclohexane in the gas s tate at 25° C, and also in t he gas state at 0° K ; the heat of format ion , from th e elemen ts, of the give n isomer in both t he liquid and gas states at 25° C and in the gas state at 0° K . The 1'c1ation of t he energy content to the s t ru cture of these molecules is di scussed , including the labeling of th e lower an d higher-boiling forms of 1,3-dimethylcyclohexane as cis and trans, respectively.

Heats of formation and isomerization of the eight C8H12 alkylcyclohexanes in the liquid and gaseous states