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Ethyl- and n- propylbenzene peroxidation has been studied in the presence of supported gold nanoparticles on TiO2(AuNP@TiO2). The decomposition products obtained from Fenton-induced cumene hydroperoxide decomposition, as well as the oxidation products of ethyl- and n- propylbenzene, implicate the participation of reactive oxygen species adsorbed on the AuNP surface. This surface intermediate is believed to be a fundamental participant in hydrogen abstraction reactions required to facilitate the formation of the observed carbonyl derived product.

journal of the brazilian chemical society

AuNP@TiO<sub>2</sub>Catalyzed Peroxidation of Ethyl- and<i>n</i>-Propylbenzene: Exploring the Interaction Between Radical Species and the Nanoparticle Surface

AuNP@TiO2Catalyzed Peroxidation of Ethyl- andn-Propylbenzene: Exploring the Interaction Between Radical Species and the Nanoparticle Surface

AuNP@TiO₂Catalyzed Peroxidation of Ethyl- andn-Propylbenzene: Exploring the Interaction Between Radical Species and the Nanoparticle Surface