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Bibliotecas de novos β-aminocetonas e γ-aminoalcoois que mostram uma grande diversidade estrutural foram facilmente obtidas a partir de uma abordagem simple, utilizando os derivados da 3-(N,N-dimetilamino)propiofenona como material de partida chave. O procedimento envolveu inicialmente a N-alquilacao de benzilaminas secundarias com derivados de propiofenona produzindo as desejadas β-aminocetonas. A reducao quimica ou catalitica dos grupos carbonilo atinge a obtencao dos γ-aminoalcoois em bons rendimentos. Este protocolo mostrou ser uma via alternativa conveniente para a sintese do anestesico local Falicain® e para a droga topica antifungica Naftifina®.

journal of the brazilian chemical society

A Straightforward and Efficient Method for the Synthesis of Diversely Substituted β-Aminoketones and γ-Aminoalcohols from 3-(<i>N,N</i>-Dimethylamino)propiophenones as Starting Materials

A Straightforward and Efficient Method for the Synthesis of Diversely Substituted β-Aminoketones and γ-Aminoalcohols from 3-(N,N-Dimethylamino)propiophenones as Starting Materials