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Polycrystalline indium tin oxide (ITO) film has a rough enzyme-sized surface structure, which efficiently enhances the direct electron transfer (DET) caused by the electrocatalytic activity of cytochrome c (cyt c). It is explained that the heme iron of cyt c was sufficiently close to the polycrystalline ITO electrode to achieve DET. Polycrystalline ITO is a suitable material for the enzyme-modified electrode of an electrochemical biosensor. © The Electrochemical Society of Japan, All rights reserved.

High Performance of DET-type Bioelectrocatalysis of Cytochrome c on Indium Tin Oxide Film Electrode with Enzyme-sized Nanostructure