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Phase-separating porous glass (PG) was studied with respect to the ion-exchange reaction of Cs+ ions from aqueous solutions, and the effect of residual sol (aluminosilicate, in particular) in the pores was examined. Cs+ uptake from solutions containing Cs+ ions only was excellent in both the presence and absence of aluminum. For solutions containing additional ions, selective adsorption of Cs+ was only observed when aluminum was present in the PG. The results show that Cs+ ion-exchange can be controlled by slight changes in the chemical composition of PG. © The Electrochemical Society of Japan, All rights reserved.

Ion-exchange of Cs+ Ions on Phase-separating Porous Glass: Effect of Residual Sol in Pores