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Electro-reductive homo-coupling of aryl bromides in a double mediatory system involving catalytic amounts of PdCl2(PPh3)2 and N-alkyl-4-alkoxycarbonylpyridinium salts was performed successfully to afford the corresponding biaryls in good to moderate yields. © The Electrochemical Society of Japan, All rights reserved.

Electro-reductive Homo-Coupling Reaction of Aryl Bromides in PdCl2(PPh3)2/Pyridinium Salt Double Mediatory Systems