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Redox properties of 2,3-diaminophenazine were investigated in acidic aqueous and acetonitrile solutions. In each case, continuous potential cycling generated deposited products, poly(2,3-diaminophenazine) (PDAP) on electrode surfaces. PDAP deposited from aqueous solution showed rather complicated redox response with reduction pre-peak that depended on the initial potential, while PDAP deposited from acetonitrile indicated well-defined adsorption species properties in acidic aqueous solution. © The Electrochemical Society of Japan, All rights reserved.

Redox Properties of 2,3-Diaminophenazine and Its Electropolymerized Product in Aqueous and Acetonitrile Solutions