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We have synthesized 3,4-ethylendioxythiophene (EDOT) monomer analogs such as 3,4-ethyleneoxythiathiophene (EOTT), 3,4-ethylenedithiathiophene (EDTT) and 3,4-methylethylenedithiathiophene (MEDTT), and investigated morphological and electrochemical properties of the corresponding polymer films prepared by their electrochemical polymerization. In addition, their properties were compared with those of poly(3,4-ethylendioxythiophene (PEDOT) film electropolymerized. © The Electrochemical Society of Japan, All rights reserved.

Morphological and Electrochemical Properties of 3,4-Substitued Polythiophene Films Prepared by Electrochemical Polymerization