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We have investigated the preparation and electrochemical characteristics of a lithium excess Li4.3Ti5O12 carbon composite (Li4.3Ti5O12/C) with different carbon sources (polyacryl acid, polyvinyl alcohol, and carboxy methyl cellulose sodium). We have prepared the lithium excess Li4.3Ti5O12/C by a spray-drying method followed by calcining at 800°C in a nitrogen atmosphere. The TEM observations indicated that the surface of the Li4.3Ti5O12/C particle was clearly covered with an amorphous carbon layer. The Li4.3Ti5O12/C materials employing polyvinyl alcohol as the carbon source showed the best rate performance with the highest discharge capacity of 117mAh (g-Li4.3Ti5O12/C) at the 10C rate. © The Electrochemical Society of Japan, All rights reserved.

Influence of the Carbon Source on the Surface and Electrochemical Characteristics of Lithium Excess Li4.3Ti5O12 Carbon Composite