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The anodic behaviors of Pd, Pt and Au have been investigated in LiCl-KCl eutectic melt at 683 K. Chemical reduction of the dissolved noble metal ions by H2 and CH4 has been also carried out. It was shown that Pd and Au could be dissolved anodically with a large dissolution rate, and that the dissolution rate of Pt was limited because of its passivation behavior. Fine particles of these noble metals were obtained by H2 or CH4 reduction though they combined together.

Anodic Dissolution and Chemical Reduction of Noble Metals in LiCl-KCl Melt