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Formal redox potentials of the U4+/U3+ and U3+/U couples in molten LiCl-RbCl eutectic were determined by cyclic voltammetry. These redox potentials were more negative than those in the LiCl-KCl eutectic but positive comparing to those in the NaCl-CsCl eutectic. This relation would be correlated with the averaged alkali cation radius.

Redox Equilibria of the U4+/U3+ and U3+/U Couples in Molten LiCl-RbCl Eutectic