English (United Kingdom)

https://curated-unify.zendy.io/wp-json/zendy-region/v1/featured_content/oa?rat=en

https://curated-unify.zendy.io/wp-json/zendy-region/v1/highlighted_journal/

Global: Zendy Plus annual

Presents the access of premium content as premium feature

Premium Content

Presents the keyphrase highlighting as premium feature

Keyphrase Highlighting

Presents the summarisation as premium feature

Summarisation

Insights

Presents the pdf analysis as premium feature

PDF Analysis

Presents the zaia usage as premium feature

ZAIA

Global: Zendy Tools annual

Global: Zendy Free Plan

Global: Zendy Tools monthly

Global: Zendy Plus monthly

The characteristics for 3,4,9,10-perylenetetracarboxylic-bisbenzimidazole (PTCBI, an n-type semiconductor) and 29H,31H-phthalocyanine (H2Pc, a p-type semiconductor) as organic p/n bilayer and bulk heterojunction (BHJ) photoelectrodes were studied for the photooxidation of thiol. Based on the analysis in their absorption spectra, a new absorption band in the longer wavelength (λ > 800nm) for both bilayer and co-deposited photoelectrode suggested a formation of charge transfer complex. A photoanodic current was observed at λ ~ 880nm for the both bilayer and co-deposited electrodes, while no absorption and photocurrent for single layers of PTCBI and H2Pc. By assuming the Langmuir adsorption equilibrium at the solid/water interface, the kinetic parameters for the photoanodic current of thiol was analyzed for the longer wavelength of irradiation (λ ~ 900nm), and it was indicated that the rate of oxidation in the co-deposited was higher than that of the bilayer due efficient charge separation in the charge transfer complex. © The Electrochemical Society of Japan, All rights reserved.

electrochemistry

Study of Co-deposition Photoelectrode of Perylene Derivative and Phthalocyanine in Comparison with Its Bilayer Focusing on Charge Transfer Complex and Kinetic Analysis