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Titanite-rich granodiorites occurring in the Austrian Mühlviertel are intimately associated with the I/S-granites of the Mauthausen/Freistadt granite suite. These rocks form small irregular bodies in granites of this granitic suite of the Moldanubian batholith that are represented by usually fine-grained and dark granodiorites, which contain a large amount of titanite hell “spots” formed by aggregates of plagioclases and quartz. Titanite as a relative plentiful accessory mineral exists in the center of these “spots” as idiomorphic and sphenoidal grains. The composition of titanite ranges from 89 to 92 mol.% titanite end-member. According to its Al concentration, the analyzed titanites could be considered as low-Al titanites (Al = 0.05–0.08 atoms per formula unit). Titanite contains low concentrations of both (Al + Fe)–OH (2–9 mol.%) and (Al + Fe)–F (0–8 mol.%). Titanite together with Na-enriched plagioclase and quartz is originated during late-magmatic evolution of titanite-spots granodiorites.

Titanite from Titanite-Spots Granodiorites of the Moldanubian Batholith (Central European Variscan Belt)