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This first chapter aims at giving a brief framework for understanding the principles of electrochemistry in corrosion and tribocorrosion, enabling potential users and readers to quickly apprehend the electrochemical nature of corrosion. The subsequent chapter will provide additional details on the methods derived from these principles in a clear manner and ready-to-use format. In particular, the implementation of electrochemical techniques for the study of tribocorrosion allows, in situ and in real time, to monitor and control the corrosion conditions during wear and to quantify the corrosion kinetics. An introductory to some of the basic terms and concepts of electrochemistry and corrosion is first presented. Then, an overview of the thermodynamic and kinetic parameters of relevance to corrosion electrochemistry is highlighted. A description on how the electrical nature of corrosion reactions allows the interface to be modeled as an electrical circuit, as well as how this electrical circuit can be used to obtain information on corrosion rates. These prerequisites are necessary to better understand the surface reactivity of metals and other electronic conductive materials immersed in ionic electrolyte media whether or not subjected to mechanical stimuli.

Electrochemical Techniques for Corrosion and Tribocorrosion Monitoring: Fundamentals of Electrolytic Corrosion