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In this chapter, the following three rare-earth complexes with amino acids, Eu(Glu) (Im)5(ClO4)3 3HClO4 6H2O, Nd(Gly)2Cl3 3H2O, and La(Glu)(Im)6(ClO4)3 4HClO4 4H2O, are synthesized and characterized by element analysis, infrared (IR) spectrum, and x-ray diffraction (XRD) analysis. The thermodynamic property studies on these complexes are performed. For the first one, Eu(Glu)(Im)5(ClO4)3 3HClO4 6H2O, the low temperature heat capacity, phase transition, and thermodynamic functions are determined by adiabatic calorimetry. For the second one, Nd(Gly)2Cl3 3H2O, the molar dissolution enthalpy and standard molar enthalpy of formation are determined by isoperibol solution reaction calorimetry. For the third one, La(Glu)(Im)6(ClO4)3 4HClO4 4H2O, the microcalorimetry is used to investigate the interaction between the complex and the Escherichia coliDH5α to elucidate the biological effects of the complex.

Thermodynamic Property Study on the Complexes of Rare- Earth Elements with Amino Aids