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It is difficult, if not hazardous and partisan, to rank the top advances of organic chemistry in the last approx. 20 years for their role in the development of this science and adjacent, complementary others. It can, however, be said with certainty that the field of homogeneous (HOHAO) and heterogeneous heterobifunctional acyclic oligomers (HEHAO) [1] of ethylene oxide, through their diversity of macromolecular architectures and effects, turns out to be one of the most significant achievements. Their importance resides mainly in the resolve by affordable means of some fundamental problems of organic synthesis by the transfer to the same phase of reaction partners with different polarities (organic substrate and water-soluble, usually inorganic, reactant).

Ethylene Oxide Homogeneous Heterobifunctional Acyclic Oligomers