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Corrosion is a great problem in a lot of chemical industries and in the systems of energy production. When metals are exposed to an aggressive environment or to atmosphere effects tend to reverse to the lesser energy state of ore. All these processes are enhanced by the aggressive conditions that sometimes can be found in the industry, high temperature and pressure or corrosive environments. Therefore, corrosion may imply a lot of economic costs in the productive system. According to NACE [1] in 2002 the cost of corrosion in USA could be established in 276 million of dollars per year. Therefore, it is quite important to develop and use techniques that can allow determining and monitoring the corrosion of the metals.

Role of Modern Localised Electrochemical Techniques to Evaluate the Corrosion on Heterogeneous Surfaces