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Restriction and an interdiction on use of toxic materials in electronics products since 2006 have promoted an intensification of development new ecologically friendly materials (glasses, glass ceramics, ceramics) with attractive properties. It has stimulated new lead (cadmium) free systems with good glass forming abilities investigations and new stoiciometric and eutectic points revealing and characterization. Alkaline-earth bismuth borate ternary systems were a good candidate for this purpose, because the binary Bi2O3-B2O3 system have propensity for glass formation and set of binary compounds and eutectics [1 3]. Furthermore, bismuth borate single crystals and glass ceramics have nonlinear optical (NLO) properties and other attrac‐ tive properties [4 7]. Both these factors are reasons for further study of binary and ternary bismuth borate systems, and the glasses which they form.

Phase Diagram of The Ternary BaO-Bi2O3-B2O3 System: New Compounds and Glass Ceramics Characterisation