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Measurements of semiconductor photocurrent (PC) spectra have a long and rich history. During the 1960s and 1970s, the topic became one of the most studied phenomena in semi‐ conductor research so that entire textbooks were dedicated to the subject [1-4]. In spite these considerable activities, only a few theoretical efforts were published in order to fit PC spec‐ tra. The first attempt is attributed to DeVore [5], who, with the purpose to find an explana‐ tion for the typically measured PC peak in the vicinity of the band gap, presumed enhanced carrier recombinations at the semiconductor surface with respect to the bulk. In other words, along the light propagating coordinate the carrier lifetime (and therefore the recom‐ bination rate) is changing. However, instead to transfer this idea directly into a mathemati‐ cal model, DeVore used the non-measurable parameter carrier surface recombination velocity in order to achieve PC fits with a peak.

Theoretical Analysis of the Spectral Photocurrent Distribution of Semiconductors