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Ionizing radiation can be used for understanding mechanism of polymerization reaction as well as for initiation of the polymerization process. Some of the advantages of the radiation initiated polymerization over conventional methods are: (i) absence of foreign matter, like initiator, catalyst, etc., (ii) polymerization at low temperature or in solid state, (iii) rate of the initiation step can easily by controlled by varying dose rate and (iv) the initiating radicals can be produced uniformly by γ-irradiation. The gamma ray induced radiation polymerization, broadly speaking, in addition to the narrow sense “radiation polymerization (also known as radiation initiated polymerization. That is, using high energy ionizing ray to irradiate monomers, and generates ions or radicals, so that form the active center and the polymerization reaction.), also includes the radiation graft polymerization and radiation crosslinking polymerization, etc. [1-18].

Bulk Preparation of Radiation Crosslinking Poly (Urethane-Imide)