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In the case of molecular liquids meaning of structure is two-fold-first is molecular units, their structure or conformation and second is average spatial arrangement of molecules or liquid structure. A liquid can not have structure in the same sense as a crystallographic solid has since the positions of the molecules continuously change and any local configuration will change over a short interval of time. In spite of that there is a possibility that, on average, a particular configuration dominates over the others, especially in H-bonded liquids. Alcohols are good examples where small labile clusters continually break and reform at a mean time interval. During the last few decades, the structural correlations in associative liquids, particularly, those involving H-bonding have been extensively studied, thanks to the successful application of statistical mechanical methods together with improved methods of experimental techniques (Diffraction, Raman, NMR) and Computer simulations. In spite of extensive developments some areas remain unclear even today. For example, the structure and structure related properties of liquid alcohols with large sized molecular species sill remain somewhat controversial. Alcohols are important group of compounds widely used as solvents and many of their properties are due to the existence of intermolecular hydrogen bonds. Though alcohols have amphiphilic molecular structures, the presence of hydrophobic groups do not allow them to form tetrahedral structure like that in water, rather they form H-bonded chains. The diffraction techniques, both x-ray and neutron have yielded useful direct information about the microscopic average structure and near neighbor correlations. The computer simulations, NMR also provide very useful information about their microscopic structure and dynamics. Although all the techniques yield general nature of the liquid structure as chains there is lot of disagreement in the detailed nature of the chain or cluster formed due to H-bonding. In solid and gaseous phases, alcohol structures are now well established. In liquid state however, the situation is still open in view of differences in the results of diffraction and other techniques (Svishchev & Kusalik, 1993; Jorgensen, 1986; Magini et al, 1982; Sarkar & Joarder, 1993, 1994; Benson, 1996).

The Molecular Conformations and Intermolecular Correlations in Positional Isomers 1- and 2- Propanols in Liquid State Through Neutron Diffraction