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The present chapter gives an overview of the application of Attenuated total reflection – Infrared spectroscopy (ATR-IR) to the environmentally important mineral – aqueous electrolyte interface. At these interfaces the important adsorption processes occur that limit the availability of potentially toxic solutes. These retention processes may retard for example the migration of solutes in aquifer systems or even immobilize them on the aquifer material, which is usually a natural mineral. Selected solutes may also via a preliminary adsorption process, which weakens bonds, enhance both dissolution kinetics and the equilibrium solubility of a given mineral.

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Attenuated Total Reflection - Infrared Spectroscopy Applied to the Study of Mineral - Aqueous Electrolyte Solution Interfaces: A General Overview and a Case Study