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Addition of chemically active compounds to flame, which are able to change the flame velocity, the flame propagation limits and the other macrokinetic parameters, seems to be the most effective way to control combustion. Of special interest are chemically active inhibitors producing a noticeable effect on flame at low concentrations, which do not change the flame stoichiometry. Thousands of elementary reactions involving hundreds of species proceed in hydrocarbon flame. However, the key reactions are those involving atoms and free radicals; with their reaction rates being much faster than those of the other reactions. The inhibitors mainly interact and affect the above processes.

Chemical Transformations in Inhibited Flames over Range of Stoichiometry