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It is accepted nowadays that the self-assembly or self-organization occurs in a system when two types of interactions exist simultaneously between various elements of a system – a short-range attraction and a long-range repulsion. If a combination of such interactions is manifested in a system, equilibrium nanostructures/nanoparticles could occur. This general principle applies for many different systems – e.g., liquid crystals, ferrofluids, lyotropic systems, surfactants and polymers. Polymers and copolymers in good solvent are widely used for creation of self-assembled nanoparticles in solution since they offer an extremely wide range of different monomers and compositions, the possibility to vary the polymer chain length and use tailor-made polymers for producing materials with specific properties and functionalities. For such polymers, no additives are required to form equilibrium nanoparticles.

Polymeric Nanoparticles Stabilized by Surfactants: Controlled Phase Separation Approach