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Rather than dwell on the mathematical derivation of the complex numerical algorithms and a repetition of the fundamentals of non-linear regression methods and least squares fitting which are available from a wide variety of sources (Martell and Motekaitis 1988; Polster and Lachmann 1989; Gans 1992; Press, Vetterling et al. 1995; Maeder and Neuhold 2007), we aim to show the experimentalist how to obtain the results they are interested, using purpose designed global analysis software and a variety of worked examples. We will be using ReactLab, a suite of versatile and powerful reaction modelling and analysis tools developed by the authors. Other academic and commercial applications exist for multivariate and related types of analysis and the reader is encouraged to explore these for comparative purposes. All offer different features and benefits but will not be discussed here.

Analysis of Chemical Processes, Determination of the Reaction Mechanism and Fitting of Equilibrium and Rate Constants