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L-rhamnose is found widely in bacteria and plants (Giraud & Naismith, 2000). It is a common component of the cell wall and the capsule of many pathogenic bacteria, and has been indicated to play an essential role in many pathogenic bacteria (Giraud & Naismith, 2000). L-rhamnose is also found in the cytoplasmic membrane of archaea (Sprott et al., 1983), while pathogenic archaea have not been identified (Eckburg et al., 2003).

The Thermostable Enzyme Genes of the dTDP-L-Rhamnose Synthesis Pathway (rmlBCD) from a Thermophilic Archaeon