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Behaviors of cationic and nonionic mixed micelles in the form of hexadecyltrimethylammonium bromide (HDABr) and hexadecyltrimethylammonium bromide-Polyethylene glycol hexadecyl ether (C 16 E 20 ), in the presence of inert salts (NaBr and 3,5-dichlorosodium benzoate), by the use of reaction probe between Pp and ionized PhSH (Pp = piperidine and PhSH = phenyl salicylate), has been reported in this work. The values of R X  Br (R X  Br denotes ion exchange constants obtained in the presence of micelles of different structural features) or K X  Br (K X  Br denotes ion exchange constants obtained in the presence of micelles of the same structural features) for 3,5-Cl 2 C 6 H 3 CO 2  - were almost the same at three different [HDABr] T (0.006, 0.010 and 0.015 M). The average value of R X  Br or K X  Br determined, in the presence of pure HDABr micelles, using semi empirical kinetic (SEK) method appeared to be almost 2½-fold larger (R X  Br or K X  Br = 198) than that in the presence of mixed HDABr-C 16 E 20 micelles (R X  Br or K X  Br = 78). Rheological measurements indicated the existence of wormlike/twisted micelles and vesicle at 0.015 M pure HDABr, various [3,5-Cl 2 C 6 H 3 CO 2 Na], and 25 and 35℃ whereas there were evidence of only spherical micelles in the presence of mixed HDABr-C 16 E 20 ([HDABr] T = 0.015 M and [C 16 E 20 ] T = 0.006 M) at both temperatures.

journal of oleo science

Study of Cationic and Nonionic Mixed Micelles with NaBr and 3,5-Cl&lt;sub&gt;2&lt;/sub&gt;C&lt;sub&gt;6&lt;/sub&gt;H&lt;sub&gt;3&lt;/sub&gt;CO&lt;sub&gt;2&lt;/sub&gt;Na by Use of Probe Nucleophilic Reaction of Piperidine with Ionized Phenyl Salicylate