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Ferrocenylsilanes with various functions at silicon (chlorine, vinyl, ethynyl) were prepared and studied by multinuclear magnetic resonance methods ( 1 H,  13 C,  29 Si NMR spectroscopy). The gasphase geometries of the silanes were optimized by calculations at the B3LYP=6-311+G(d,p) level of theory, and NMR parameters (chemical shifts δ13C, δ29Si, spin-spin coupling constants) were calculated at the same level of theory.

Vinylsilylferrocenes and Ethynyl(vinyl)silylferrocenes. Synthesis, Multinuclear Magnetic Resonance Study and DFT Calculations