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The double phosphate KLuP 2 O 7  doped with Pr 3+  ions was prepared by solid-state reaction. The material obtained was characterized by powder X-ray diffraction. The luminescence spectroscopy and the excited state dynamics of this material were studied upon excitation with VUV synchrotron radiation. The 5d-4 f emission of Pr 3+  upon both direct and band gap excitation was detected and assigned. The decay kinetics of the Pr 3+  5d-4 f emission is characterized by a decay time of about 20 ns and is nearly temperature independent within the range 8 - 300 K. Both dynamics and energy transfer peculiarities revealed in the study suggested good potentials for application of KLuP 2 O 7 :Pr 3+  as a fast scintillator material.

Synchrotron Radiation Study of Interconfigurational 5d-4f Luminescence of Pr 3+ in KLuP 2 O 7