English (United Kingdom)

https://curated-unify.zendy.io/wp-json/zendy-region/v1/featured_content/oa?rat=en

https://curated-unify.zendy.io/wp-json/zendy-region/v1/highlighted_journal/

Zendy Open

Presents the pdf analysis as premium feature

PDF Analysis

Insights

Presents the summarisation as premium feature

Summarisation

Presents the keyphrase highlighting as premium feature

Keyphrase Highlighting

Presents the zaia usage as premium feature

ZAIA

Zendy Tools

Zendy Plus

Presents the access of premium content as premium feature

Premium Content

By heating of FeCl 2  and MnCl 2  in the ionic liquid [BMIm][OTf] (BMIm: 1-butyl-3- methylimidazolium, OTf: trifluoromethanesulfonate), the compounds [BMIm][M(OTf) 3 ] (M: Fe +II , Mn +II ) have been obtained as colorless crystals. Similarly, [BMIm][Li(OTf) 2 ] was synthesized by heating of LiCl in [BMIm][OTf]. While the crystal quality of the [BMIm][M(OTf) 3 ] (M: Fe +II , Mn +II ) products thus obtained is low, mild oxidation of Fe(CO) 5  or Mn2(CO) 10  with GeI 4  applied as an alternative in the same ionic liquid allowed a slow growth of well-formed, needle-shaped crystals. According to X-ray structure analysis based on single crystals, [BMIm][M(OTf) 3 ] (M: Fe +II , Mn +II ) crystals are monoclinic, and [BMIm][Li(OTf) 2 ] crystals are triclinic. All compounds form infinite  1  ∞ [M(OTf) 3 ] (M=Fe, Mn) and  1  ∞ [Li(OTf) 2 ] chains. The compounds have further been characterized by FT-IR spectroscopy, energy-dispersive X-ray analysis (EDX), differential thermal analysis (DTA), thermogravimetry (TG), and magnetic measurements.

[BMIm][Fe(OTf) 3 ], [BMIm][Mn(OTf) 3 ], [BMIm][Li(OTf) 2 ] – Three One-dimensional Infinite Coordination Polymers