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Structural analyses were performed to determine the local structure of liquid TiCl 4  using laboratory-scale X-ray diffraction and Raman spectroscopy from which the existence of tetrahedral TiCl 4  molecules in the liquid was definitely confirmed. Conventionally, in molten salts, the valence increase of the central metal ion, for example in the range from 1 to 3, leads to more complicated liquid structures, yet a further increase in valence is usually accompanied by an enhanced covalency, forming stable tetrahedral molecules like e. g. CCl 4 .We discuss the intermolecular structure of TiCl 4  liquid as well as the intramolecular one.

The Local Structure of Liquid TiCl4 Analyzed by X-Ray Diffraction and Raman Spectroscopy